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i wontOriginally Posted by Kell78dogg
I could point something out here, but I'll just quote you.Originally Posted by KnowledgeTheFoundation
Accept how to capitalize, punctuate, and the simple fact Jordan is better THAN Kobe.Originally Posted by kobeskool2009
im tha realest dude on here
i kno err thing
Tool.
Originally Posted by kobeskool2009
im tha realest dude on here
i kno err thing
Football or Basketball?Originally Posted by kobeskool2009
Originally Posted by tmukg21
what grade are you in?
im a senior lil homie
umma ball d1 next year
ya dig
Temperature of the steam jacket = 99[sup]o[/sup]C.
Volume of air in the gas syringe = 7cm[sup]3[/sup].
Initial mass of the hypodermic syringe plus liquid = 8.36g
Final mass of the hypodermic syringe = 8.21g
Volume of vapour plus air = 84 cm[sup]3[/sup]
Atmospheric pressure = 753 mmHg.
[h2]Questions 38 to 40[/h2]
- If the value of the gas constant R = 0.082 atm litres /[sup]o[/sup]C / mole, the relative molecular mass of the liquid is given by
[table][tr][td][size=+1]0.15 x 0.082 x 0.084[/size][/td] [/tr][/table]
[size=+1]372 x 753[/size]
[table][tr][td][size=+1]0.15 x 99 x 753[/size][/td] [/tr][/table]
[size=+1]0.077 x 0.082 x 760[/size]
[table][tr][td][size=+1]0.082 x 372 x 760[/size][/td] [/tr][/table]
[size=+1]0.15 x 77 x 753[/size]
[table][tr][td][size=+1]0.15 x 0.082 x 372 x 760[/size][/td] [/tr][/table]
[size=+1]0.077 x 753[/size]
[table][tr][td][size=+1]0.082 x 0.77 x 753[/size][/td] [/tr][/table]
[size=+1]0.15 x 99[/size]
- Which of the following experimental errors would cause the value of the relative molecular mass, calculated fromt he experimental results, to be LOWER than the correct value?
[table][tr][td][size=+1]Injection of a bubble of air, in addition to the liquid, into the gas syringe.
Injection oc the liquid so that some of it remained int he neck of the gas syringe.
Leakage of the vapour from the gas syringe through the rubber cap.
Evaporation of some of the liquid from the hypodermic syringe between the two weighings.
Measuring the volume of vapour and air before it had reached the temperature of the steam jacket.[/size][/td] [td][/td] [/tr][/table]- Which of the following modifications to the experimental procedure would improve the accuracy of the value of the relative molecular mass calculated from the results?
[table][tr][td][size=+1]Finding the mass of liquid used by weighing the gas syringe and again when the liquid has been added, instead of weighing the hypodermic syringe.
Repeating the experimental using different masses of the liquid, measuring the volume of vapour produced each time and then using these results graphically to determine the density of the vapour.
Omitting the air from the gas syringe.
Using a smaller mass of the liquid.
Heating the gas syringe with an electric light bulb instead of using steam.[/size][/td] [td][/td] [/tr][/table]- A similar experiment at 130[sup]o[/sup]C using ethanoic acid, CH[sub]3[/sub]CO[sub]2[/sub]H, as the liquid gave a value for its relative molecular mass of 120 instead of the expected value of 60.
An explanation for this result could be that under the conditions of the experiment
[table][tr][td][size=+1]the volume of the ethanoic acid molecules is NOT negligible in comparison with the total volume of the vapour.
ethanoic acid vapour exists in the form of the dimer (CH[sub]3[/sub]CO[sub]2[/sub]H)[sub]2[/sub].
the molecule of ethanoic acid partially dissociates CH[sub]3[/sub]CO[sub]2[/sub]H[sub](g)[/sub]š H[sup]+[/sup][sub](g)[/sub] + CH[sub]3[/sub]CO[sub]2[/sub][sup]-[/sup][sub](g)[/sub]
ethanoic acid decomposes to methane and carbon dioxide: CH[sub]3[/sub]CO[sub]2[/sub]H[sub](g)[/sub][emoji]174[/emoji] CH[sub]4(g)[/sub] + CO[sub]2(g)[/sub]
vapours of volatile liquids deviate from ideal gas behaviour[/size][/td] [td][/td] [/tr][/table]
These questions concern rates of hydrolysis of some halogenalkanes. Three halogenalkanes were tested in the following manner: 1 cm[sup]3[/sup] of ethanolwas placed in a test tube and 3 drops of the halogenalkane were added. The test tube was placed in a water bath and heated to 60[sup]o[/sup]C. 2 cm[sup]3[/sup]of 0.l Molar silver nitrate was then added.
[h2]Questions 41 to 45[/h2]
- Why was the ethanol added?
[table][tr][td][size=+1]It indicates when the silver halide has been precipitated.
It prevents the immediate precipitation of the silver halide.
It acts as an electrophile.
It catalyses the reaction.
It acts as a solvent for the halogenoalkane.[/size][/td] [td][/td] [/tr][/table]- The experiment was carried out on four halogenoalkanes, and the appearance of the liquid three minutes after the start of the heating was noted. Here are the results:
1-chloro-butane: Clear
1-bromo-butane: Cloudy
1-iodo-butane: Heavy precipitate
Which of the following best explains these results?
[table][tr][td][size=+1]The solubility products of the silver halides decreases as you go down the halogens from chlorine to iodine.
The strength of a carbon-chlorine bond is stronger than that of a carbon-bromine bond, which is in turn greater than a carbon-iodine bond.
The three reactions occur through three totally different mechanisms.
The electronegativities of the halogens decrease as you go down the group from chlorine to iodine.
The halogens increase in size as you go down the group.[/size][/td] [td][/td] [/tr][/table]- Which of the following, which are all isometric chloropentanes, would produce a precipitate most quickly in a similar experiment?
[table][tr][td][size=+1]CH[sub]3[/sub]CH[sub]2[/sub]C(CH[sub]3[/sub])[sub]2[/sub]Cl
CH[sub]3[/sub]C(CH[sub]3[/sub])[sub]2[/sub]CH[sub]2[/sub]Cl
CH[sub]3[/sub]CH[sub]2[/sub]CHClCH[sub]2[/sub]CH[sub]3[/sub]
CH[sub]3[/sub]CH[sub]2[/sub]CH[sub]2[/sub]CHClCH[sub]3[/sub]
CH[sub]3[/sub]CH[sub]2[/sub]CH[sub]2[/sub]CH[sub]2[/sub]CH[sub]2[/sub]Cl[/size][/td] [td][/td] [/tr][/table]
These questions involve five different types of bonding. Which of the following bonding types accounts for each of the phenomena named?
[h2]Questions 46 to 50[/h2]
- The melting points of halogens decrease as you go up the group from iodine to fluorine.
[table][tr][td][size=+1]Ionic bonds
Hydrogen bonds
Dative covalent bonding
Dipole-dipole interactions
Van de Waals' forces[/size][/td] [td][/td] [/tr][/table]- Silver chloride (AgCl) dissolves in ammonia solution.
[table][tr][td][size=+1]Ionic bonds
Hydrogen bonds
Dative covalent bonding
Dipole-dipole interactions
Van de Waals' forces[/size][/td] [td][/td] [/tr][/table]- Ammonia (NH[sub]3[/sub]) reacts with boron trifluoride (BF[sub]3[/sub]).
[table][tr][td][size=+1]Ionic bonds
Hydrogen bonds
Dative covalent bonding
Dipole-dipole interactions
Van de Waals' forces[/size][/td] [td][/td] [/tr][/table]- Phosphine (PH[sub]3[/sub]) has a lower boiling point than ammonia (NH[sub]3[/sub]).
[table][tr][td][size=+1]Ionic bonds
Hydrogen bonds
Dative covalent bonding
Dipole-dipole interactions
Van de Waals' forces[/size][/td] [td][/td] [/tr][/table]- Ethoxyethane boils at a lower temperature than butan-1-ol.
[table][tr][td][size=+1]Ionic bonds
Hydrogen bonds
Dative covalent bonding
Dipole-dipole interactions
Van de Waals' forces[/size][/td] [td][/td] [/tr][/table]
For each of the following chemical reactions, select the correct type of the reaction. They are all either addition or substitution reactions.
[table][tr][td][/td] [td] [size=+1]
[/size] [table][tr][td][size=+1]Nucleophilic addition
Nucleophilic substitution
Electrophilic addition
Electrophilic substitution
Free radical substitution[/size][/td] [td][/td] [/tr][/table][/td] [/tr][/table]
[table][tr][td][/td] [td]
[table][tr][td][size=+1]Nucleophilic addition
Nucleophilic substitution
Electrophilic addition
Electrophilic substitution
Free radical substitution[/size][/td] [td][/td] [/tr][/table][/td] [/tr][/table]
[table][tr][td][/td] [td] [size=+1]
[/size] [table][tr][td][size=+1]Nucleophilic addition
Nucleophilic substitution
Electrophilic addition
Electrophilic substitution
Free radical substitution[/size][/td] [td][/td] [/tr][/table][/td] [/tr][/table]
[table][tr][td][size=+1]CH[sub]3[/sub]CHO + HCN [emoji]174[/emoji] CH[sub]3[/sub]CH(OH)CN[/size][/td] [td] [size=+1]
[/size] [table][tr][td][size=+1]Nucleophilic addition
Nucleophilic substitution
Electrophilic addition
Electrophilic substitution
Free radical substitution[/size][/td] [td][/td] [/tr][/table][/td] [/tr][/table]
[table][tr][td][size=+1]C[sub]6[/sub]H[sub]13[/sub]Br + OH[sup]-[/sup][emoji]174[/emoji] C[sub]6[/sub]H[sub]13[/sub]OH + Br[sup]-[/sup][/size][/td] [td] [size=+1]
[/size] [table][tr][td][size=+1]Nucleophilic addition
Nucleophilic substitution
Electrophilic addition
Electrophilic substitution
Free radical substitution[/size][/td] [td][/td] [/tr][/table][/td] [/tr][/table]
Originally Posted by gaseousfashion
Who killed JFK?
Originally Posted by FreshPrince
why did bush knock down the towers?
yea me too. OCD FTLOriginally Posted by FL0ETiCNOSTALGiA
your title makes me cringe.
Originally Posted by dreClark
Football or Basketball?Originally Posted by kobeskool2009
Originally Posted by tmukg21
what grade are you in?
im a senior lil homie
umma ball d1 next year
ya dig
At Mizzou I presume?
i aint playin at mizzou
i gots scholarship fo both
i aint kno if i doin bball or fball yet