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There's a window of opportunity to always land an excellent/great throw on tyranitar where he can't attack. It occurs just after he dips his head down and can be seen clearly at the end of this video between the 338-342 mark.
Hope the loophole helps you all capture your tyranitar raid boss! I was lucky enough to catch a perfect one today using this method.
When I went raiding in SF, a guy told me exactly when to throw it. I used that same tactic on a Lapras today. Just when they're bringing their head up from their attack is when I throw it.